Energy Conversion Materials Laboratory

The majority of the world’s energy sources are currently non-renewable.  Additionally, most energy sources reject waste-heat as a result of typical conversion inefficiencies. The vision of the Energy Conversion Materials Laboratory is to recover this waste-heat, therefore increasing the efficiency of the world’s current energy sources, and to ultimately offer a solid-state, renewable solution.

The Energy Conversion Materials Laboratory works towards this goal by gaining a fundamental understanding of thermal-to-electrical transport in solid-state materials.  Characterizing coupled thermal, electrical, and magnetic transport can offer insight into transport mechanisms that can increase energy conversion efficiency, moving novel materials closer towards device viability.

Conventional Thermoelectric Energy Conversion

In conventional thermoelectric energy conversion, heat is converted into electricity.  When a material is placed between a heat source (potentially waste-heat) and a heat sink, a temperature differential exists.  This temperature differential drives charge carrier (electrons and holes) movement, which induces an electrical current that could be used as an output voltage.  Traditional thermoelectric materials are semiconductors, where n-type and p-type couples are connected electrically in series and thermally in parallel as shown in the figure below.  To make a thermoelectric module, multiple thermoelectric couples are connected.  Here, the temperature gradient and electrical current run parallel to one another in what is called the longitudinal geometry.

N-type and p-type materials connected electrically in series and thermally in parallel.  A temperature difference drives a parallel electrical current moving from an electrode at the hot end to the cold end in the n-type material and cold to hot in the p-type material such that it is returned to an electrode on the hot side.

Although semiconductors are the most widely used thermoelectric materials, they do have their downfalls – semiconductors are brittle, made of uncommon materials, and typically expensive.  Furthermore, output in the longitudinal geometry scales intrinsically with material properties; in order to increase the output of a device, pairs of n-type and p-type thermoelectric materials must be added to the module, creating extra electrical connections and resistive losses.

Transverse Thermoelectric Energy Conversion

When the temperature gradient and electrical current are geometrically separated, such as in the transverse geometry shown in the figure below, the output actually scales extrinsically with the size of the device (meaning that to grow the output voltage, the material would simply need to be lengthened in that direction).  Additionally, the need for both n-type and p-type thermoelectric materials is eliminated since the voltage output can be measured in an isothermal plane due to the orthogonality in the directions of the applied temperature gradient and output voltage.

A material placed in a temperature gradient with a perpendicular externally applied magnetic field.  The output voltage is mutually perpendicular to the applied temperature gradient and external magnetic field.

Despite these device advantages, the transverse geometry does need an extra force to push charge carrier movement perpendicular to the temperature gradient, which is found in the Lorentz force.  The cross product between an externally applied magnetic field, Happ||z, and a perpendicular temperature gradient results in a force driving electron movement in the third perpendicular direction, resulting in a voltage output mutually orthogonal to both the applied temperature gradient and external magnetic field.

In the longitudinal geometry, both holes and electrons move in the same direction (condensing on the cold side).  But in the transverse geometry, the magnetic field causes electrons and holes to scatter in opposite directions, where electrons accumulate on one side of the material and holes accumulate on the other.  This lends two-carrier systems, such as semimetals, to be strong candidates for thermoelectric transport in this geometry.

Topological Semimetals

Weyl semimetals were not experimentally discovered until 2015 in TaAs.  This discovery has opened doors for studying unique states of matter in solid-state systems.  Weyl semimetals offer unique signatures depicted in the band structure figure below: linear Dirac bands near their crossing points (shown by dashed yellow lines), crossing points called Weyl nodes that always come in pairs due to the breaking of inversion symmetry or time-reversal symmetry (shown inside the blue circles), opposite chirality at the Weyl points (indicated by the blue positive and negative signs), and sources/sinks of Berry curvature at said Weyl points (indicated by the arrows depicting the directionality of the wave function enforced by the conduction and valence bands respectively).

Band structure of a Weyl semimetal (energy vs. momentum vectors).  Conduction and valence bands have crossed.  Bands are linear near the crossing points, which are called Weyl points.  These Weyl points serve as sources or sinks of Berry curvature as induced by the directionality of the wave functions of the corresponding bands.

Topological semimetals specifically are expected to demonstrate strong thermoelectric transport in the transverse geometry due to the access to both holes and electrons and their ultra-high mobility.  Their other unique signatures found in their band structure are also expected to contribute to transport in novel ways.

Current Projects

Research in the Energy Conversion Materials Laboratory is motivated by the principles of thermoelectric transport and its potential applications in novel systems.  Here, we seek to answer the following questions (this is not an exhaustive list):

  • Are all topological materials effective at transverse thermoelectric transport?
  • Can a Berry curvature, or other intrinsic magnetic structure, replace the need for an external magnetic field in a transverse geometry?
  • What and how do other unique transport signatures in topological materials contribute to thermoelectric transport?
  • Can simpler, more consumer-friendly materials be developed to exhibit similar transport signature as topological materials?
  • Can charge transport and thermal transport be independently separated in a way to increase the thermoelectric conversion efficiency of a material?


Characterization of coupled thermal, electrical, and magnetic transport in bulk materials

Materials properties, including but not limited to:

  • Seebeck Effect
  • Nernst Effect
  • Hall Effect
  • Thermal Hall Effect
  • Electrical Resistivity
  • Magnetoresistance
  • Thermal Conductivity
  • Heat Capacity
  • Magnetic Moment

Customizable measurements and controls with options for the following conditions:

  • Temperature range of 1.8 K to 400 K
  • Magnetic field range of -9 T to +9 T
  • Evacuated environment during measurement
  • Isothermal and adiabatic sample mounts
  • Nanovolt measurement sensitivity
  • Sample preparation in an argon environment


Quantum Design (QD) DynaCool Physical Property Measurement System (PPMS)

  • Temperature range of 1.8 K to 400 K
  • Superconducting magnet with range of -9 T to +9 T
  • High vacuum chamber
  • Electrical breakout box combined with LabVIEW controls for customized, automated experiments
  • QD Resistivity Measurement System
  • QD Electrical Transport Option (ETO)
  • QD Heat Capacity Measurement System
  • QD Thermal Transport Option (TTO)
  • QD Vibrating System Magnetometer (VSM)

Customized cryostat station

  •  Janis continuous flow liquid nitrogen cryostat (with option for liquid helium)
  • Temperature range of 78 K to 400 K (lower with liquid helium)
  • Lakeshore EM4 electromagnet with range of -1.2 T to +1.2 T
  • High vacuum capability
  • Instrumentation and LabVIEW controls for customized, automated experiments


  • Argon environment for oxygen-free storage and sample preparation
  • Sight-glass integrated microscope for preparing samples for measurement

Open Positions

The Energy Conversion Materials Laboratory is currently recruiting researchers!  Students pursuing their PhD, MS, or BS in mechanical or materials engineering at UC are encouraged to email Dr. Watzman (please attach your CV or resume).


408 Rhodes Hall
University of Cincinnati’s Uptown West Campus

Principal Investigator

Headshot of Sarah June Watzman

Sarah June Watzman

Assistant Professor, CEAS - Mechanical Eng



Assistant Professor, Mechanical Engineering
August 2018 - present
Department of Mechanical and Materials Engineering
University of Cincinnati
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